非传统稳定同位素分析技术要点     

白江昊  刘芳  张兆峰  安亚军  李欣  薛永丽  徐玉明 《地学前缘》2020,27(3):1-13

高精度高质量的同位素分析技术是开展非传统稳定同位素地球化学工作的前提。同位素分析是不断提取样品真实信息的过程,包括样品制备、化学分离、质谱测定和数据处理4个基本步骤。在同位素分析过程中,每一环节都有可能引入空白或者污染,或造成同位素分馏,引发信息“失真”。为了准确获得样品的真实同位素组成,必须有效避免污染并精准校正在分析过程中可能的干扰。以Ca同位素为例,在总结前人工作的基础上,探讨了各个步骤所涉及的分析要点,为建立其他同位素体系的分析方法提供参考,为后续储库探讨、机理解析及应用研究提供技术支撑。  相似文献   

关键金属元素分析测试技术方法应用进展   总被引：7，自引：5，他引：2  

李超  王登红  屈文俊  孟会明  周利敏  樊兴涛  李欣尉  赵鸿  温宏利  孙鹏程 《岩矿测试》2020,39(5):658-669

以稀有、稀散、稀土、铂族元素为主体的战略性关键金属矿产资源,在新材料、新能源和信息技术等新兴产业中发挥着越来越关键的作用。随着我国关键矿产资源地质调查的不断深入,关键金属元素以其赋存基体复杂、不同矿物含量差异大、化学性质不稳定等特点对分析测试技术提出了新的挑战。本文根据化学组成不同,对关键金属元素主要赋存基体进行了分类,主要分为硅酸盐、碳酸盐、硫酸盐、钨酸盐、磷酸盐、氧化物、硫化物、卤化物等。对于不同的基体岩石矿物,通常采用酸溶法(硝酸-氢氟酸组合、王水)或碱熔法等传统溶样方法进行化学消解。评述了当前关键金属元素测试常用的电子探针、电感耦合等离子体质谱、电感耦合等离子体发射光谱、X射线荧光光谱等仪器的特点及应用,总结了关键金属元素分析过程中出现的样品难溶解、回收率不完全、测试过程氧化物和同质异位素干扰、样品和标准基体不一致等常见问题,并提出了相应的解决方案。微区原位分析凭借其高效率、低成本、高空间分辨率的优势,以及野外现场分析凭借其简单快速、贴近野外工作的特点是关键金属元素测试技术发展的主要趋势。  相似文献   

A note on the consolidation settlement of a rigid circular foundation on a poroelastic halfspace          下载免费PDF全文

Jueun Kim  A.P.S. Selvadurai 《国际地质力学数值与分析法杂志》2016,40(14):2003-2016

This paper uses Biot's poroelasticity approach to examine the consolidation behaviour of a rigid foundation with a frictionless base in contact with a poroelastic halfspace. The mathematical development of the mixed boundary value problem involves a set of dual integral equations in the Laplace transform domain which cannot be conveniently solved by employing conventional procedures. In this paper, a numerical solution is developed using a scheme where the contact normal stress is approximated by a discretized equivalent. The influence of limiting drainage boundary conditions at the entire surface of the halfspace on the degree of consolidation of the rigid circular foundation is investigated. The results obtained in this study are compared with the corresponding results given in the literature. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

GPS网中基准点的数量及位置分布对精度的影响分析     

李金生  杨学锋  马驰 《全球定位系统》2010,35(2):30-32

GPS网中，基准点的数量、组合方式及其分布位置都将影响到GPS网的定位精度，不合理的组合和分布方式也会影响GPS网固有的高精度。为了获取高质量的GPS定位成果，布设高等级控制网时必须要科学地选择基准点的数量及其分布，以便找到最佳组合方案。通过工程实例，分析了GPS网中基准点组合及分布方法，得出了相关结论。  相似文献   

塔河油田地面工程信息系统的设计与探讨     

申成祎 《测绘与空间地理信息》2010,33(1):122-123,126,130

着重探讨了塔河油田地面工程信息系统的建设思路和实现方法,针对油田的实际,以当前先进的组件式地理信息系统软件MAPGIS和可视化编程工具Microsoft Visual Studio构架的技术体系为基础,开发一套方便实用的油田地面工程信息系统。本系统建设为集原油集输、天然气和油田伴生气集输、道路、输供电线路为一体的可视化数据平台,实现了整个油田数据采集、管线图绘制,以及信息的浏览、查询统计、综合管理等功能。  相似文献   

The role of eddies in solute transport and recovery in rock fractures: Implication for groundwater remediation          下载免费PDF全文

Seung Hyun Lee  In Wook Yeo  Kang‐Kun Lee  Won Sang Lee 《水文研究》2017,31(20):3580-3587

A better understanding of solute transport and retention mechanism in rock fractures has been challenging due to difficulty in their direct observations in microscale rough‐walled fractures. Six representative troughs in a rough‐walled fracture were selected for microscale observations of eddy formation with increasing flow velocity and its effect on spatiotemporal changes of solute concentration. This experimental study was enabled by a microscale visualization technique of micro particle image velocimetry. With increasing flow velocity (Re ≤ 2.86), no eddies were generated, and solutes along the main streamlines transported rapidly, whereas those near the wall moved slowly. A larger amount of solutes remained trapped at all troughs at Re = 2.86 than Re < 1. For Re = 8.57, weak eddies started to be developed at the troughs on the lee side, which little contributed to overall solute flushing in the fracture. Accordingly, a large of amount of water was needed for solute flushing. The flow condition of 1 < Re < 10, before a full development of eddies, was least favourable in terms of time and amount of remediation fluid required to reach a target concentration. After large eddies were fully developed at troughs on the lee side for Re = 17.13, solutes were substantially reduced by eddies with less amount of water. Fully developed eddies were found to enhance solute transport and recovery, as opposed to a general consensus that eddies trap and delay solutes. Direct inflow into troughs on the stoss side also made a great contribution to solute flushing out of the troughs. This study indicates that fully developed eddies or strong inflows at troughs are highly possible to form for Re > 10 and this flow range could be favourable for efficient remediation.  相似文献   

A practical and efficient numerical scheme for the analysis of steady state unconfined seepage flows     

Mohammad Hossein Bazyar  Adel Graili 《国际地质力学数值与分析法杂志》2012,36(16):1793-1812

The scaled boundary finite‐element method (SBFEM), a novel semi‐analytical technique, is applied to the analysis of the confined and unconfined seepage flow. This method combines the advantages of the finite‐element method and the boundary element method. In this method, only the boundary of the domain is discretized; no fundamental solution is required, and singularity problems can be modeled rigorously. Anisotropic and nonhomogeneous materials satisfying similarity are modeled without additional efforts. In this paper, SBFE equations and solution procedures for the analysis of seepage flow are outlined. The accuracy of the proposed method in modeling singularity problems is demonstrated by analyzing seepage flow under a concrete dam with a cutoff at heel. As only the boundary is discretized, the variable mesh technique is advisable for modeling unconfined seepage analyses. The accuracy, effectiveness, and efficiency of the method are demonstrated by modeling several unconfined seepage flow problems. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Analysis of the spatial variation of heavy metals in the Guadiana Estuary sediments (SW Iberian Peninsula) based on GIS-mapping techniques     

J. Delgado  J.M. Nieto  T. Boski 《Estuarine, Coastal and Shelf Science》2010

This work reveals the usefulness of the GIS (Geographic Information Systems) mapping techniques to show the distribution of pollutants along an estuarine environment, as the final stage of a thorough study. In the case of study, the environmental quality of the sediments in the Guadiana river estuary was determined by means of a complete geochemical characterization consisting on the calculation of enrichment factors for the most important metals and metalloids (compared with the local background of non-contaminated sediments). The obtained results were depicted in “enrichment distribution maps” which evidenced a distribution of the elements in two groups: Group-I, elements with natural origin (Al, Fe, Mn, Co, and Cr) distributed homogeneously along the basin, and Group-II, elements associated to anthropic origin (As, Cd, Cu, Pb, Ni and Zn) with clear punctual sources besides a high concentration all over the estuary. The enrichment factors for the elements of Group-II are indicative of the existence of a noticeable diffuse historical mining pollution associated with the acid mine drainage generated in the internal zones of the basin, which could overlap minor pollution inputs from other human activities. The obtained results lead us to a reconsideration of the traditionally thought “unpolluted” environment when it was compared to nearby estuaries.  相似文献   

RTK技术在沛县新城区图根控制测量中的应用     

詹家民  周杨 《全球定位系统》2010,35(1):38-42

叙述了RTK技术在沛县新城区图根控制测量中的应用，通过比较分析说明：RTK的测量精度完全能够满足1：500地形测图图根控制的精度要求。  相似文献   

Simulation of evapotranspiration and carbon dioxide flux in the wheat‐maize rotation croplands of the North China Plain using the Simple Biosphere Model     

Huimin Lei  Dawen Yang  Yanjun Shen  Yu Liu  Yucui Zhang 《水文研究》2011,25(20):3107-3120

The North China Plain, which is critical for food production in China, is encountering serious water shortage due to heavy agricultural water requirement. The accurate modelling of carbon dioxide flux and evapotranspiration (ET) in croplands is thus essential for yield prediction and water resources management. The land surface model is powerful in simulating energy and carbon dioxide fluxes between land and atmosphere. Some key processes in the Simple Biosphere Model (Version 2, SiB2) were parameterized based on the observations. The simulated fluxes were tested against the eddy covariance flux measurements over two typical winter wheat/maize double cropping fields. A simple diagnostic parameterisation of soil respiration, not included in SiB2, was added and calibrated using the observations to model the carbon budget. The Ball‐Berry stomatal conductance model was calibrated using observed leaf gas exchange rate, showing that the original SiB2 could significantly underpredict the ET in the wheat field. SiB2 significantly underpredicted soil resistance at the Weishan site, leading to overpredict the ET. Overall, there was a close agreement between the simulated and observed latent heat fluxes and net CO₂ exchange using the re‐parameterized SiB2. These findings are important when the model is used for the regional simulation in the North China Plain. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献